Aritz Aduriz scored a stunning winning goal against Barcelona to match a feat only ever achieved by Lionel Messi in LaLiga.
With Lionel Messi absent and Luis Suarez suffering a first-half injury, Barcelona were poor in their 1-0 defeat to Athletic Bilbao.
With Lionel Messi already sidelined, Barcelona lost Luis Suarez to injury early in their game against Athletic Bilbao.
Philippe Coutinho looks certain to swap LaLiga for the Bundesliga after Barcelona confirmed a loan deal with Bayern Munich has been agreed.
Antoine Griezmann and Frenkie de Jong will make their first LaLiga appearances for Barcelona, but Philippe Coutinho is not involved.
Rodrigo's collapsed move to Atletico Madrid enhances Valencia's prospects of competing in the Champions League, according to boss Marcelino.
Real Madrid start their LaLiga campaign at Celta Vigo on Saturday and Gareth Bale, James Rodriguez and Luka Jovic could all play a part.
Real Madrid may be without new signing Eden Hazard until September after confirming an injury for the Belgium star.
Real Madrid's pre-season has been typically hectic but Zinedine Zidane was in a relaxed mood ahead of their LaLiga opener at Celta Vigo.
Gareth Bale returned to action for Real Madrid last week and Zinedine Zidane has challenged the winger "to make things difficult" for him.